From 8e0003a7f7b1cb5bb75f5037388847cf4579e711 Mon Sep 17 00:00:00 2001 From: hackbard Date: Fri, 19 Oct 2007 16:48:36 +0200 Subject: [PATCH] added solid state physics tutorial 1 --- solid_state_physics/tutorial/1_01.tex | 83 +++++++++++++++++++++++++++ 1 file changed, 83 insertions(+) create mode 100644 solid_state_physics/tutorial/1_01.tex diff --git a/solid_state_physics/tutorial/1_01.tex b/solid_state_physics/tutorial/1_01.tex new file mode 100644 index 0000000..fac0acb --- /dev/null +++ b/solid_state_physics/tutorial/1_01.tex @@ -0,0 +1,83 @@ +\pdfoutput=0 +\documentclass[a4paper,11pt]{article} +\usepackage[activate]{pdfcprot} +\usepackage{verbatim} +\usepackage{a4} +\usepackage{a4wide} +\usepackage[german]{babel} +\usepackage[latin1]{inputenc} +\usepackage[T1]{fontenc} +\usepackage{amsmath} +\usepackage{ae} +\usepackage{aecompl} +\usepackage[dvips]{graphicx} +\graphicspath{{./img/}} +\usepackage{color} +\usepackage{pstricks} +\usepackage{pst-node} +\usepackage{rotating} + +\setlength{\headheight}{0mm} \setlength{\headsep}{0mm} +\setlength{\topskip}{-10mm} \setlength{\textwidth}{17cm} +\setlength{\oddsidemargin}{-10mm} +\setlength{\evensidemargin}{-10mm} \setlength{\topmargin}{-1cm} +\setlength{\textheight}{26cm} \setlength{\headsep}{0cm} + +\renewcommand{\labelenumi}{(\alph{enumi})} + +\begin{document} + +% header +\begin{center} + {\LARGE {\bf Materials Physics I}\\} + \vspace{8pt} + Prof. B. Stritzker\\ + WS 2007/08\\ + \vspace{8pt} + {\Large\bf Tutorial 1} +\end{center} + +\section{Free electron in a box} +Our understanding of condensed matter is based on the idea of heavy, positively charged ions and light, negatively charged valence electrons. +In order to describe such a system of interacting particles you have to solve the full Hamiltonian +\begin{eqnarray} + H &=& H_{ion} + H_{el} + H_{ion-el} \nonumber \\ + &=& H_{ion,kin} + H_{ion-ion} + H_{el,kin} + H_{el-el} + H_{ion-el} \nonumber +\end{eqnarray} +which accounts for the ionic and electronic subsystem as well as the coupling between these two. + +Lighter valence electrons move much faster than the nuclei and thus follow the ionic motion adiabatically. +For the electrons the nuclei appear fixed in position. +On the other way round the electrons appear blurred to the nuclei adding an extra term to an effective potential. +This is called the Born-Oppenheimer or adiabatic approximation basically switching off electron-phonon interactions. + +Having separated the ionic and electronic degrees of freedom the Hamiltonian still involves all electronic coordinates which results in a many-particle wave function as a solution of the Schr"odinger equation depending on the positions of all electrons. +By completely neglecting the electron-electron interaction the Hamiltonian can be written as a sum of single particle Hamiltonians +\[ + H = \sum_i - \frac{\hbar^2}{2m} \nabla_i^2 + v_{ext}({\bf r}_i) +\] +where $v_{ext}$ is the combination of ion-electron and a constant ion-ion interaction. +This is called the independent electron approximation. + +Thus, it is sufficient to consider a single electron located in an effective time-independent potential due to the static ions and all other electrons. +Since most materials condense into almost perfect periodic arrays the periodicity should also hold for the potential style. + +Within this tutorial even the periodic potential is simplified. +Consider a single particle (mass $m$) enclosed in a box (side length $L=V^{1/3}$) where the potential is constant ($V_0$) inside the box and infinite at the surface. + +\begin{enumerate} + \item Write down the Schr"odinger equation and boundary conditions + for the particle enclosed in the box. + \item Find a solution of the Schr"odinger equation. + Write down the wave function and energy eigenvalues. + {\bf Hint:} Apply separation of variables: + $\Psi({\bf r})=F_x(x)F_y(y)F_z(z)$. + \item Write down the wave function of the ground state and calculate the + zero-point energy (energy of the ground state). + \item What are the values allowed for $k_x$, $k_y$ and $k_z$ + in reciprocal space? + Sketch a cross section perpendicular to the $k_x$ and $k_y$ axis + showing some values allowed for $k_x$ and $k_y$. +\end{enumerate} + +\end{document} -- 2.39.2