X-Git-Url: https://hackdaworld.org/gitweb/?p=lectures%2Flatex.git;a=blobdiff_plain;f=physics_compact%2Fqm.tex;h=bf8b2ee13966c27c22f6ddd5b223af65a63b3286;hp=8e65f4c789c057f49da7bde109cf8cec2938e23f;hb=4069f849b1973e2eb9020fa2e190f93b56537c60;hpb=5898b999f5d72857fa765fd544262e7c0104042e diff --git a/physics_compact/qm.tex b/physics_compact/qm.tex index 8e65f4c..bf8b2ee 100644 --- a/physics_compact/qm.tex +++ b/physics_compact/qm.tex @@ -6,13 +6,18 @@ \label{sec:var_meth} The variational method constitutes a promising approach to estimate the ground-state energy $E_0$ of a system for which exact solutions are unknown. + +\begin{theorem}[Variational method] Considering a {\em trial ket} $|\tilde 0\rangle$, which tries to imitate the true ground-state ket $|0\rangle$, it can be shown that \begin{equation} \tilde E\equiv\frac{\langle \tilde 0|H|\tilde 0\rangle}{\langle \tilde 0|\tilde 0\rangle} \ge E_0 \textrm{ ,} \end{equation} i.e.\ an upper bound to the ground-state energy can be obtained by considering various kinds of $|\tilde 0\rangle$. -To proof this, $|\tilde 0\rangle$ is expanded by the exact energy eigenkets $|k\rangle$ with +\end{theorem} + +\begin{proof} +The trial function $|\tilde 0\rangle$ is expanded by the exact energy eigenkets $|k\rangle$ with \begin{equation} H|k\rangle = E_k|k\rangle\text{ ,} \qquad E_0\leq E_1\leq\ldots\leq E_k\ldots \text{ ,} @@ -38,6 +43,8 @@ Since $\langle k|k'\rangle=\delta_{k k'}$, $H|k\rangle = E_k|k\rangle$ and $E_k\ \label{sec:vm_f} \end{equation} which proofs the variational theorem. +\end{proof} + Moreover, equality in \eqref{sec:vm_f} is only achieved if $|\tilde 0\rangle$ coincides exactly with $|0\rangle$, i.e.\ if the coefficients $\langle k|\tilde 0\rangle$ all vanish for $k\neq 0$. \chapter{Quantum dynamics}