-The probability of finding C, which will be most stable at sites for which the number of neighbors equals the natural valence, i.e. substitutionally on a regular Si site of a perfect lattice, is, thus, reduced at substitutional lattice sites and likewise increased to be found as an interstitial.
-Depending on the way C is incorporated and whether precipitation occurs or not the volume is either reduced in the case of substitutionally incorporated C or expanded in the case of C interstitial formation \cite{goesele85}.
-
-There are, however, ...
-In implanted Si the location of C is to a great deal incorporated as an interstitial atom due to a reduced topological contraint.
-Other methods exist to realize only substitutional C.
-
-% -> my own links: strane etc ...
-% -> skorupa 3.5: heterostructures
-
-\section{Assumed cubic silicon carbide conversion mechanisms}
+The probability of finding C, which will be most stable at sites for which the number of neighbors equals the natural valence, i.e. substitutionally on a regular Si site of a perfect lattice, is, thus, reduced at substitutional lattice sites and likewise increased at interstitial sites.
+Indeed, x-ray rocking curves reveal a positive lattice strain, which is decreased but still remains with increasing annealing temeprature, indicating the location of the majority of implanted C atoms at interstitial sites \cite{isomae93}.
+Due to the absence of dislocations in the implanted region interstitial C is assumed to prevent clustering of implantation-induced Si self-interstitials by agglomeration of C-Si interstitials or the formation of SiC precipitates accompanied by a relaxation of the lattice strain.
+
+% link to strain engineering
+However, there is great interest to incorporate C onto substitutional lattice sites, which results in a contraction of the Si lattice due to the smaller covalent radius of C compared to Si \cite{baker68}, causing tensile strain, which is applied to the Si lattice.
+Thus, substitutional C enables strain engineering of Si and Si/Si$_{1-x}$Ge$_x$ heterostructures \cite{yagi02,chang05,osten97}, which is used to increase charge carrier mobilities in Si as well as to adjust its band structure \cite{soref91,kasper91}.
+% increase of C at substitutional sites
+Epitaxial layers with \unit[1.4]{at.\%} of substitutional C have been successfully synthesized in preamorphized Si$_{0.86}$Ge$_{0.14}$ layers, which were grown by CVD on Si substrates, using multiple-energy C implantation followed by solid-physe epitaxial regrowth at \unit[700]{$^{\circ}$C} \cite{strane93}.
+The tensile strain induced by the C atoms is found to compensates the compressive strain present due to the Ge atoms.
+Studies on the thermal stability of Si$_{1-y}$C$_y$/Si heterostructures formed in the same way and equal C concentrations showed a loss of substitutional C accompanied by strain relaxation for temperatures ranging from \unit[810-925]{$^{\circ}$C} and the formation of spherical 3C-SiC precipitates with diameters of \unit[2-4]{nm}, which are incoherent but aligned to the Si host \cite{strane94}.
+During the initial stages of precipitation C-rich clusters are assumed, which maintain coherency with the Si matrix and the associated biaxial strain.
+Using this technique a metastable solubility limit was achieved, which corresponds to a C concentration exceeding the solid solubility limit at the Si melting point by nearly three orders of magnitude and, furthermore, a reduction of the defect denisty near the metastable solubility limit is assumed if the regrowth temperature is increased by a rapid thermal annealing process \cite{strane96}.
+By MBE ... \cite{powell93,osten99}
+
+\section{Assumed silicon carbide conversion mechanisms}