-In the so called Lely process,
-Lely (sublimation)
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-modified Lely or modified sublimation
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-though significant advances have been achieved a bunch of defects ...
+In the so called Lely process, a tube of porous graphite is surrounded by polycrystalline SiC as gained by previously described processes.
+Heating the hollow carbon cylinder to \unit[2500]{$^{\circ}$C} leads to sublimation of the material at the hot outer wall and diffusion through the porous graphite tube followed by an uncontrolled crystallization on the slightly cooler parts of the inner graphite cavity resulting in the formation of randomly sized, hexagonally shaped platelets, which exibit a layered structure of various alpha polytypes with equal \hkl{0001} orientation.
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+Subsequent research \cite{tairov78,tairov81} resulted in the implementation of a seeded growth sublimation process wherein only one large crystal of a single polytype is grown.
+In the so called modified Lely or modified sublimation process nucleation occurs on a SiC seed crystal located at the top or bottom of a cylindrical growth cavity.
+As in the Lely process, SiC sublimes at a temperature of \unit[2400]{$^{\circ}$C} from a polycrystalline source diffusing through a porous graphite retainer along carefully adjusted thermal and pressure gradients.
+Controlled nucleation occurs on the SiC seed, which is held at approximately \unit[2200]{$^{\circ}$C}.
+The growth process is commonly done in a high-purity argon atmosphere.
+The method was successfully applied to grow 6H and 4H boules with diameters up to \unit[60]{mm} \cite{tairov81,barrett91,barrett93,stein93}.
+This refined versions of the physical vapor transport (PVT) technique enabled the reproducible boule growth of device quality SiC crystals, which were for instance used to fabricate blue light emitting diodes with increased quantum efficiencies \cite{hoffmann82}.
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+Although significant advances have been achieved in the field of SiC bulk crystal growth, a variety of problems remain.
+The high temperatures required in PVT growth processes limit the range of materials used in the hot zones of the reactors, for which mainly graphite is used.
+The porous material constitutes a severe source of contamination ...
+
+These defects include growth spirals (stepped screw dislocations), subgrain boundaries as well as micropipes (micron sized voids extending along the c axis of the crystal) in the hexagonal polytypes.