finished polytypes slide
[lectures/latex.git] / posic / talks / seminar_2010.tex
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23 %\usepackage{epic}
24 %\usepackage{eepic}
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27 \graphicspath{{../img/}}
28
29 \usepackage[setpagesize=false]{hyperref}
30
31 \usepackage{semcolor}
32 \usepackage{semlayer}           % Seminar overlays
33 \usepackage{slidesec}           % Seminar sections and list of slides
34
35 \input{seminar.bug}             % Official bugs corrections
36 \input{seminar.bg2}             % Unofficial bugs corrections
37
38 \articlemag{1}
39
40 \special{landscape}
41
42 % font
43 %\usepackage{cmbright}
44 %\renewcommand{\familydefault}{\sfdefault}
45 %\usepackage{mathptmx}
46
47 \usepackage{upgreek}
48
49 \begin{document}
50
51 \extraslideheight{10in}
52 \slideframe{none}
53
54 \pagestyle{empty}
55
56 % specify width and height
57 \slidewidth 27.7cm 
58 \slideheight 19.1cm 
59
60 % shift it into visual area properly
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68
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71
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77 \newrgbcolor{lachs}{1.0 .93 .81}
78
79 % topic
80
81 \begin{slide}
82 \begin{center}
83
84  \vspace{16pt}
85
86  {\LARGE\bf
87   Atomistic simulation study of the silicon carbide precipitation
88   in silicon
89  }
90
91  \vspace{48pt}
92
93  \textsc{F. Zirkelbach}
94
95  \vspace{48pt}
96
97  Lehrstuhlseminar
98
99  \vspace{08pt}
100
101  17. Juni 2010
102
103 \end{center}
104 \end{slide}
105
106 % motivation / properties / applications of silicon carbide
107 \begin{slide}
108
109 \small
110
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112
113
114
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118  \pspolygon[linecolor=hlbb,fillcolor=hlbb,fillstyle=solid](6.75,0.5)(8,2)(8,2)(6.75,3.5)
119
120  \rput[lt](0.2,4.6){\color{gray}PROPERTIES}
121
122  \rput[lt](0.5,4){wide band gap}
123  \rput[lt](0.5,3.5){high electric breakdown field}
124  \rput[lt](0.5,3){good electron mobility}
125  \rput[lt](0.5,2.5){high electron saturation drift velocity}
126  \rput[lt](0.5,2){high thermal conductivity}
127
128  \rput[lt](0.5,1.5){hard and mechanically stable}
129  \rput[lt](0.5,1){chemically inert}
130
131  \rput[lt](0.5,0.5){radiation hardness}
132
133  \rput[rt](13.3,4.6){\color{gray}APPLICATIONS}
134
135  \rput[rt](13,3.85){high-temperature, high power}
136  \rput[rt](13,3.5){and high-frequency}
137  \rput[rt](13,3.15){electronic and optoelectronic devices}
138
139  \rput[rt](13,2.35){material suitable for extreme conditions}
140  \rput[rt](13,2){microelectromechanical systems}
141  \rput[rt](13,1.65){abrasives, cutting tools, heating elements}
142
143  \rput[rt](13,0.85){first wall reactor material, detectors}
144  \rput[rt](13,0.5){and electronic devices for space}
145
146 \end{pspicture}
147
148 \begin{picture}(0,0)(-10,68)
149 \includegraphics[width=2.6cm]{wide_band_gap.eps}
150 \end{picture}
151 \begin{picture}(0,0)(-295,-165)
152 \includegraphics[width=3cm]{sic_led.eps}
153 \end{picture}
154 \begin{picture}(0,0)(-215,-165)
155 \includegraphics[width=2.5cm]{6h-sic_3c-sic.eps}
156 \end{picture}
157 \begin{picture}(0,0)(-313,65)
158 \includegraphics[width=2.2cm]{infineon_schottky.eps}
159 \end{picture}
160 \begin{picture}(0,0)(-220,65)
161 \includegraphics[width=2.9cm]{sic_wechselrichter_ise.eps}
162 \end{picture}
163
164 \end{slide}
165
166 % contents
167
168 \begin{slide}
169
170 {\large\bf
171  Outline
172 }
173
174  \begin{itemize}
175   \item Fabrication of silicon carbide and different polytypes
176   \item Precipitation model of 3C-SiC in Si
177   \item Utilized simulation techniques
178         \begin{itemize}
179          \item Molecular dynamics (MD) simulations
180          \item Density functional theory (DFT) calculations
181         \end{itemize}
182   \item C and Si self-interstitial point defects in silicon
183   \item Precipitation simulations
184   \item Summary / Conclusion / Outlook
185  \end{itemize}
186
187 \end{slide}
188
189 % start of contents
190
191 \begin{slide}
192
193  {\large\bf
194   Polytypes of SiC
195  }
196
197  \vspace{4cm}
198
199  \small
200
201 \begin{tabular}{l c c c c c c}
202 \hline
203  & 3C-SiC & 4H-SiC & 6H-SiC & Si & GaN & Diamond\\
204 \hline
205 Hardness [Mohs] & \multicolumn{3}{c}{------ 9.6 ------}& 6.5 & - & 10 \\
206 Band gap [eV] & 2.36 & 3.23 & 3.03 & 1.12 & 3.39 & 5.5 \\
207 Break down field [$10^6$ V/cm] & 4 & 3 & 3.2 & 0.6 & 5 & 10 \\
208 Saturation drift velocity [$10^7$ cm/s] & 2.5 & 2.0 & 2.0 & 1 & 2.7 & 2.7 \\
209 Electron mobility [cm$^2$/Vs] & 800 & 900 & 400 & 1100 & 900 & 2200 \\
210 Hole mobility [cm$^2$/Vs] & 320 & 120 & 90 & 420 & 150 & 1600 \\
211 Thermal conductivity [W/cmK] & 5.0 & 4.9 & 4.9 & 1.5 & 1.3 & 22 \\
212 \hline
213 \end{tabular}
214
215 {\tiny
216  Values for $T=300$ K
217 }
218
219 \begin{picture}(0,0)(-160,-155)
220  \includegraphics[width=7cm]{polytypes.eps}
221 \end{picture}
222 \begin{picture}(0,0)(-10,-185)
223  \includegraphics[width=3.8cm]{cubic_hex.eps}\\
224 \end{picture}
225 \begin{picture}(0,0)(-10,-175)
226  {\tiny cubic (twist)}
227 \end{picture}
228 \begin{picture}(0,0)(-60,-175)
229  {\tiny hexagonal (no twist)}
230 \end{picture}
231 \begin{pspicture}(0,0)(0,0)
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239 \end{pspicture}
240
241 \end{slide}
242
243 \begin{slide}
244
245  {\large\bf
246   Fabrication of silicon carbide
247  }
248
249  \small
250  
251  \vspace{4pt}
252
253  SiC - \emph{Born from the stars, perfected on earth.}
254  
255  \vspace{4pt}
256
257  Conventional thin film SiC growth:
258  \begin{itemize}
259   \item \underline{Sublimation growth using the modified Lely method}
260         \begin{itemize}
261          \item SiC single-crystalline seed at $T=1800 \, ^{\circ} \text{C}$
262          \item Surrounded by polycrystalline SiC in a graphite crucible\\
263                at $T=2100-2400 \, ^{\circ} \text{C}$
264          \item Deposition of supersaturated vapor on cooler seed crystal
265         \end{itemize}
266   \item \underline{Homoepitaxial growth using CVD}
267         \begin{itemize}
268          \item Step-controlled epitaxy on off-oriented 6H-SiC substrates
269          \item C$_3$H$_8$/SiH$_4$/H$_2$ at $1100-1500 \, ^{\circ} \text{C}$
270          \item Angle, temperature $\rightarrow$ 3C/6H/4H-SiC
271          \item High quality but limited in size of substrates
272         \end{itemize}
273   \item \underline{Heteroepitaxial growth of 3C-SiC on Si using CVD/MBE}
274         \begin{itemize}
275          \item Two steps: carbonization and growth
276          \item $T=650-1050 \, ^{\circ} \text{C}$
277          \item Quality and size not yet sufficient
278         \end{itemize}
279  \end{itemize}
280
281  \begin{picture}(0,0)(-280,-65)
282   \includegraphics[width=3.8cm]{6h-sic_3c-sic.eps}
283  \end{picture}
284  \begin{picture}(0,0)(-280,-55)
285   \begin{minipage}{5cm}
286   {\tiny
287    NASA: 6H-SiC and 3C-SiC LED\\[-7pt]
288    on 6H-SiC substrate
289   }
290   \end{minipage}
291  \end{picture}
292  \begin{picture}(0,0)(-265,-150)
293   \includegraphics[width=2.4cm]{m_lely.eps}
294  \end{picture}
295  \begin{picture}(0,0)(-333,-175)
296   \begin{minipage}{5cm}
297   {\tiny
298    1. Lid\\[-7pt]
299    2. Heating\\[-7pt]
300    3. Source\\[-7pt]
301    4. Crucible\\[-7pt]
302    5. Insulation\\[-7pt]
303    6. Seed crystal
304   }
305   \end{minipage}
306  \end{picture}
307
308 \end{slide}
309
310 \end{document}